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Fluorine-containing imines. Communication 6. Reaction of hexafluoroacetone perfluoropivaloylimine with dimethylantline and dimethylbenzylamine

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Hexafluoroacetone perfluoropivaloylimine reacts with dimethylaniline as a C-alkylating agent and with dimethyIbenzylimine and triethylamine as a hydride-ion acceptor: the reactions are accompanied by the ejection of perfluoro-tert-butyl anions, which leads to the formation of isocyanates.

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Literature cited

  1. N. P. Gambaryan, D. P. Del'tsova, and Z. V. Safronova, Izv. Akad. Nauk SSSR, Ser. Khim., 1814 (1987).

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    N. P. Gambaryan, D. P. Del'tsova, Z. V. Safronova & G. S. Kaitmazova

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  1. N. P. Gambaryan
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  2. D. P. Del'tsova
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  3. Z. V. Safronova
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  4. G. S. Kaitmazova
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Additional information

See [1] for Communication 5.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2022–2024, September, 1987.

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Gambaryan, N.P., Del'tsova, D.P., Safronova, Z.V. et al. Fluorine-containing imines. Communication 6. Reaction of hexafluoroacetone perfluoropivaloylimine with dimethylantline and dimethylbenzylamine. Russ Chem Bull 36, 1873–1875 (1987). https://doi.org/10.1007/BF00958334

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  • DOI: https://doi.org/10.1007/BF00958334

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