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Principles of the conformational structure of vicinal halohydrins and their methyl ethers

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The most probable conformation for bieyclo[4.1.0]heptane halohydrin derivatives and their methyl ether analogs in the carane series is a 1,2-diplanar form (anti-sofa) with a diequatorial arrangement of substituents.

  2. 2.

    Vicinal halohydrins exist in a gauche-gauche conformation of the Hal-C-C-OR chain, with a 1,3-parallel bond orientation; in the case of methoxyhalo derivatives, this structure is present at equilibrium.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    É. Kh. Kazakova, S. V. Andreeva, G. A. Bakaleinik, G. I. Kovylyaeva, R. R. Shagidullin & A. N. Vereshchagin

Authors
  1. É. Kh. Kazakova
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  2. S. V. Andreeva
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  3. G. A. Bakaleinik
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  4. G. I. Kovylyaeva
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  5. R. R. Shagidullin
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  6. A. N. Vereshchagin
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1992–1997, September, 1987.

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Kazakova, É.K., Andreeva, S.V., Bakaleinik, G.A. et al. Principles of the conformational structure of vicinal halohydrins and their methyl ethers. Russ Chem Bull 36, 1846–1850 (1987). https://doi.org/10.1007/BF00958327

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  • DOI: https://doi.org/10.1007/BF00958327

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