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Stereochemical structure of phosphorus-containing heterocycles. 41.Molecular structure of 2-diethylamino-4,5,7,8-dinaphtho-[1,2:1′,2′]-6H-1,3,2-dioxaphosphocin

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Conclusions

According to the data from x-ray crystallographic analysis, the molecule of 2-diethylamino-4,5,7,8-dinaphtho[1,2:1′,2′]-6.H-1,3,2-dioxaphosphocin has an unsymmetrical boat conformation with dialkylamlno group in the equatorial position and with greatly elongated endocyclic P-O bonds (to 1.667 Å).

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Branch, Academy of Sciences of the USSR, USSR

    I. A. Litvinov, O. N. Kataeva, V. A. Naumov, R. P. Arshinova & B. A. Arbuzov

Authors
  1. I. A. Litvinov
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  2. O. N. Kataeva
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  3. V. A. Naumov
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  4. R. P. Arshinova
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  5. B. A. Arbuzov
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Additional information

For Communication 40, see [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1985–1988, September, 1987.

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Litvinov, I.A., Kataeva, O.N., Naumov, V.A. et al. Stereochemical structure of phosphorus-containing heterocycles. 41.Molecular structure of 2-diethylamino-4,5,7,8-dinaphtho-[1,2:1′,2′]-6H-1,3,2-dioxaphosphocin. Russ Chem Bull 36, 1839–1842 (1987). https://doi.org/10.1007/BF00958325

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  • DOI: https://doi.org/10.1007/BF00958325

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