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Homogeneous synthesis of aromatic alcohols from iron carbonyl complexes of phenylacetylene, CO, and H2

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The homogeneous stoichiometric reaction of synthesis of aromatic alcohols in the reaction of iron carbonyl complexes of phenylacetylene with CO and H2, the model of analogous heterogeneous synthesis on a melted iron catalyst, was conducted.

  2. 2.

    Complexes with a binuclear structure exhibit significantly higher reactivity than mononuclear complexes.

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Authors and Affiliations

  1. A. V. Tapchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    E. V. Slivinskii, L. I. Zvezdkina, Yu. B. Kagan, Yu. P. Boitsekhovskii, M. V. Shishkina & S. M. Loktev

Authors
  1. E. V. Slivinskii
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  2. L. I. Zvezdkina
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  3. Yu. B. Kagan
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  4. Yu. P. Boitsekhovskii
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  5. M. V. Shishkina
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  6. S. M. Loktev
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Additional information

Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No, 9, pp. 1947–1951, September, 1987.

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Slivinskii, E.V., Zvezdkina, L.I., Kagan, Y.B. et al. Homogeneous synthesis of aromatic alcohols from iron carbonyl complexes of phenylacetylene, CO, and H2 . Russ Chem Bull 36, 1804–1807 (1987). https://doi.org/10.1007/BF00958317

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  • DOI: https://doi.org/10.1007/BF00958317

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