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Reaction of cluster niobium chalcogenides with n-butyllithium

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The reaction of cluster niobium chalcogenides with n-BuLi in hexane at ∼20°C has been studied. The phases obtained have been characterized by various physicochemical methods and are considered to be lithium intercalates based on the initial phases. The measured values of the Knight shifts of the lithium atoms in all the intercalates indicate a charge on these atoms close to +1.

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Literature cited

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, Novosibirsk

    A. V. Mishchenko, V. E. Fedorov & Yu. I. Mironov

Authors
  1. A. V. Mishchenko
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  2. V. E. Fedorov
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  3. Yu. I. Mironov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1931–1933, September, 1987.

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Mishchenko, A.V., Fedorov, V.E. & Mironov, Y.I. Reaction of cluster niobium chalcogenides with n-butyllithium. Russ Chem Bull 36, 1789–1790 (1987). https://doi.org/10.1007/BF00958313

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  • DOI: https://doi.org/10.1007/BF00958313

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