Advertisement

Mechanism of gas-phase oxidation of hydrogen sulfide at high temperatures

  • A. V. Chernysheva
  • V. Ya. Basevich
  • V. I. Vedeneev
  • V. S. Arutyunov
Physical Chemistry

Abstract

A kinetic model of oxidation of hydrogen sulfide is proposed. The model contains 201 elementary stages, 23 particles, and satisfactorily describes the experimental data in a wide range of temperatures and pressures.

Keywords

Oxidation Hydrogen Experimental Data Sulfide Kinetic Model 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    N. M. Émanuél', Zh. Fiz. Khim.,14, 863 (1940).Google Scholar
  2. 2.
    N. M. Émanuél', Kinetics of Chain Oxidation Reactions [in Russian], Izd. Akad. Nauk SSSR, Moscow (1950), p. 79.Google Scholar
  3. 3.
    N. M. Émanuél', Zh. Fiz. Khim.,19, 15 (1945).Google Scholar
  4. 4.
    N. N. Semenov, Some Problems in Chemical Kinetics and Reactivity [in Russian], Izd. Akad. Nauk SSSR, Moscow (1958), p. 605.Google Scholar
  5. 5.
    Yu. M. Gershenzon, A. B. Nalbandyan, and G. A. Sachyan, Dokl. Akad. Nauk SSSR,163, 927 (1965).Google Scholar
  6. 6.
    G. A. Sachyan, Yu. M. Gershenzon, and A. B. Nalbandyan, Dokl. Akad. Nauk SSSR,175, 1378 (1967).Google Scholar
  7. 7.
    C. P. Cullis and M. F. R. Mulcahy, Combust. Flame,18, 225 (1972).Google Scholar
  8. 8.
    V. G. Fedotov, Candidate Dissertation in Physical-Mathematical Sciences, Moscow (1977).Google Scholar
  9. 9.
    C. H. Muller, K. Schofield, M. Steinberg, and H. P. Broida, Proc. 17th Int. Symp. on Combustion, Pittsburgh Combustion Inst. (1979), p. 867.Google Scholar
  10. 10.
    M. F. Frenclach, J. H. Lee, J. N. White, and W. C. Gardiner, Combust. Flame,41, 1 (1981).Google Scholar
  11. 11.
    S. I. Tseregounis and O. I. Smith, Proc. 10th Int. Symp. on Combustion, Pittsburgh Combustion inst. (1985), p. 761.Google Scholar
  12. 12.
    V. Ya. Basevich, Usp. Khim.,56, 705 (1987).Google Scholar
  13. 13.
    V. P. Glushko (ed.), Thermodynamic Properties of Individual Substances [in Russian], Nauka, Moscow (1978–1979).Google Scholar
  14. 14.
    S. Benson, Chem. Rev.,78, No. 1, 23 (1976).Google Scholar
  15. 15.
    P. Gray and M. E. Sherrington, J. Chem. Soc., Faraday Trans. 1,70, No. 12, 2338 (1974).Google Scholar
  16. 16.
    P. A. Tesner, R. Kh. Rubinov, and I. Sh. Sherov, Gaz. Prom., No. 9, 28 (1984).Google Scholar
  17. 17.
    P. Roth, R. Iohr, and U. Barner, Combust. Flame,45, 273 (1982).Google Scholar
  18. 18.
    J. I. Tiee, F. B. Wampler, R. C. Oldenborg, and W. W. Rice, Chem. Phys. Lett.,82, No. 1, 80 (1981).Google Scholar
  19. 19.
    L. T. Cupitt and G. P. Glass, Int. J. Chem. Kinet., No. 1, 39 (1975).Google Scholar
  20. 20.
    D. Perner and Th. Franken, Ber. Bunsenges Phys. Chem.,73, 897 (1969).Google Scholar
  21. 21.
    D. Micelcic and R. N. Shindler, Ber. Bunsenges Phys. Chem.,74, 1280 (1970).Google Scholar
  22. 22.
    W. B. Denmoore, J. J. Margitan, M. J. Molina, et al., Chemical Kinetics and Photochemical Data for Use In Stratospheric Modeling Evaluation, No. 7, JPL Publ. 85-37, NASA, California Institute of Technology.Google Scholar
  23. 23.
    W. B. Demore, J. J. Margitan, M. J. Molina, et al., Int. J. Chem. Kinet.,17, 1135 (1985).Google Scholar
  24. 24.
    K. Chung, J. G. Calvert, and J. W. Bottenheim, Int. J. Chem. Kinet.,7, No. 2, 161 (1975).Google Scholar
  25. 25.
    J. E. Hardy and W. C. Gardiner, Jr., Proc. 16th Symp. on Combustion (1977), p. 985.Google Scholar
  26. 26.
    P. Borrel, C. J. Cobos, A. E. Croce de Cobos, et al., Ber. Bunsenges Phys. Chem.,89, No. 3, 337 (1985).Google Scholar
  27. 27.
    C. J. Cobos, H. Hippler, and J. Troe, J. Phys. Chem.,89, No. 9, 1778 (1985).Google Scholar
  28. 28.
    A. Grillo, R. Reed, and M. W. Slach, Proc. 12th Symp. on Shock Tube Waves (1980), p. 486.Google Scholar
  29. 29.
    A. Grillo, R. Reed, and M. W. Slach, J. Chem. Phys.,70, No. 4, 1634 (1979).Google Scholar
  30. 30.
    A. A. Westenberg and N. De Haas, J. Chem. Phys.,63, 5411 (1975).Google Scholar
  31. 31.
    Shie Ning Wang, O. I. Smith, and S. Tseregounis, Int. J. Chem. Kinet.,14, No. 6, 679 (1982).Google Scholar
  32. 32.
    A. B. Callear, Proc. R. Soc. London,A276, 401 (1963).Google Scholar
  33. 33.
    S. W. Mayers and L. Schiler, J. Phys. Chem.,72, 236 (1968).Google Scholar
  34. 34.
    W. B. DeMore, L. J. Stief, D. M. Golden, et al., Chemical Kinetic and Photochemical Data for Use in Stratospheric Modelling, NASA JPL Publ., CA (1981).Google Scholar
  35. 35.
    G. W. Harris, R. Atkinson, and J. N. Pitts, Chem. Phys. Lett.,69, 378 (1980).Google Scholar
  36. 36.
    C. J. Halstead and D. R. Jenkins, J. Chem. Soc, Faraday Trans.,65, Nos. 563–564, 3013 (1969).Google Scholar
  37. 37.
    R. A. Duri, G. M. Johnson, and M. Y. Smith, Combust. Flame,17, No. 2, 197 (1971).Google Scholar
  38. 38.
    D. L. Baulch, D. D. Drysdale, J. Duxbury, and S. J. Grand, Evaluated Kinetic Data for High Temperature Reactions, Vol. 3, Butterworths, London (1976).Google Scholar
  39. 39.
    J. P. Burrown, D. I. Cliff, G. W. Harris, et al., Proc. R. Soc. London,A368, 1735 (1979).Google Scholar
  40. 40.
    W. A. Payne, L. J. Stief, and D. D. Davis, J. Am. Chem. Soc.,95, No. 23, 7613 (1973).Google Scholar
  41. 41.
    R. A. Graham, A. M. Winer, R. Atkinson, and J. N. Pitts, J. Phys. Chem.,83, No. 12, 1563 (1979).Google Scholar
  42. 42.
    V. P. Bulatov, O. M. Sarkisov, M. Z. Kozliner, and V. M. Egorov, Khim. Fiz.,5, No. 8, 1031 (1986).Google Scholar
  43. 43.
    C. J. Howard, Communication at 17th Symp. on Free Radicals, Granby, CO (1985), p. 18.Google Scholar
  44. 44.
    K. Saito, Y. Uedo, and R. Yto, Int. J. Chem. Kinet.,18, 871 (1986).Google Scholar
  45. 45.
    G. Black, J. Chem. Phys., No. 3, 1345 (1986).Google Scholar
  46. 46.
    D. C. Astolz, K. Glanzer, and J. Troe, Proc 11th Int. Symp. Shock Tube and Waves, Washington Press, Seattle (1977), p. 232.Google Scholar
  47. 47.
    H. J. Plach and J. Troe, Int. J. Chem. Kinet.,16, 1531 (1984).Google Scholar
  48. 48.
    J. N. Dryscall and P. Warneo, J. Phys. Chem.,72, 3736 (1968).Google Scholar
  49. 49.
    M. A. Nettleton and R. Stirling, Proc. 12th Int. Symp. on Combustion (1969), p. 635.Google Scholar
  50. 50.
    Th. Just and G. Rimpel, Proc. 11th Symp. on Shock Tube and Shock Wave Res., Seattle (1977), p. 226.Google Scholar
  51. 51.
    D. H. Stedman, H. Alward, and A. Bauer-Blocker, J. Phys. Chem.,78, 1248 (1974).Google Scholar
  52. 52.
    A. J. Hills, R. J. Cicerone, J. G. Calvert, and J. W. Rikks, J. Phys. Chem.,91, No. 5, 1199 (1987).Google Scholar
  53. 53.
    G. Schönle, M. M. Rahman, and R. N. Schindler, Ber. Bunsenges Phys. Chem.,91, No. 1, 66 (1987).Google Scholar
  54. 54.
    N. S. Wang, E. R. Lovejoy, and C. J. Howard, J. Phys. Chem.,91, 5745 (1987).Google Scholar
  55. 55.
    R. A. Stachik and M. J. Molina, J. Phys. Chem.,91, 4603 (1987).Google Scholar
  56. 56.
    B. S. Agrawalla and D. W. Setsez, J. Chem. Phys.,86, No. 10, 5421 (1987).Google Scholar
  57. 57.
    Y. U. Lin Lin, N. S. Wang, and Y. P. Lee, Int. J. Chem. Kinet.,17, No. 11, 1201 (1985).Google Scholar
  58. 58.
    P. Devolder, C. Lafage, and L. R. Scohet, Proc. 9th Int. Symp. on Gas Kinetics, Bordeaux (1986).Google Scholar
  59. 59.
    C. Lafage, J. F. Pauvels, M. Carlier, and P. Devolder, J. Chem. Soc., Faraday Trans.,83, 731 (1987).Google Scholar
  60. 60.
    F. E. Davidson, A. R. Clemo, G. L. Duncan, et al., Mol. Phys.,46, No. 1, 33 (1982).Google Scholar
  61. 61.
    A. R. Clemo, F. E. Davidson, G. L. Duncan, and R. Grice, Chem. Phys. Lett.,84, 509 (1981).Google Scholar
  62. 62.
    E. R. Lovejoy, N. S. Wang, and C. J. Howard, J. Phys. Chem.,91, No. 22, 5749 (1987).Google Scholar
  63. 63.
    D. Martin, G. L. Jourdain, and J. Le Bras, Proc. 9th Int. Symp. on Gas Kinetics, Bordeaux (1986).Google Scholar
  64. 64.
    D. Martin, G. L. Jourdain, and J. Le Bras, J. Phys. Chem.,90, No. 17, 4143 (1986).Google Scholar
  65. 65.
    J. F. Gleason, A. Sinha, and C. J. Howard, J. Phys. Chem.,91, 719 (1987).Google Scholar

Copyright information

© Plenum Publishing Corporation 1991

Authors and Affiliations

  • A. V. Chernysheva
    • 1
  • V. Ya. Basevich
    • 1
  • V. I. Vedeneev
    • 1
  • V. S. Arutyunov
    • 1
  1. 1.N. N. Semenov Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

Personalised recommendations