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Photochemical, thermal, and thermocatalytic reactions of diphenyldiazomethane with dimethyl thiophosphite

  • B. A. Arbuzov
  • A. M. Polozov
  • N. A. Polezhaeva
  • A. Kh. Mustafin
  • Ya. A. Levin
  • É. I. Gol'dfarb
Brief Communications
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Conclusions

The direct photolysis of diphenyldiazomethane in dimethyl thiophosphite gave the product of P-H insertion. The thermal reaction leads to the N-dimethoxythiophosphorylhydrazone of benzophenone and O,O-dimethyl S-(diphenylmethyl) thiophosphate. Carbenoid P-H insertion occurred in the thermocatalytic decomposition.

Keywords

Dimethyl Photolysis Benzophenone Thermal Reaction Direct Photolysis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • B. A. Arbuzov
    • 1
  • A. M. Polozov
    • 1
  • N. A. Polezhaeva
    • 1
  • A. Kh. Mustafin
    • 1
  • Ya. A. Levin
    • 1
  • É. I. Gol'dfarb
    • 1
  1. 1.A. M. Butlerov Institute of ChemistryV. I. Ul'yanov-Lenin Kazan State UniversityUSSR

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