Photochemical, thermal, and thermocatalytic reactions of diphenyldiazomethane with dimethyl thiophosphite

  • B. A. Arbuzov
  • A. M. Polozov
  • N. A. Polezhaeva
  • A. Kh. Mustafin
  • Ya. A. Levin
  • É. I. Gol'dfarb
Brief Communications
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Conclusions

The direct photolysis of diphenyldiazomethane in dimethyl thiophosphite gave the product of P-H insertion. The thermal reaction leads to the N-dimethoxythiophosphorylhydrazone of benzophenone and O,O-dimethyl S-(diphenylmethyl) thiophosphate. Carbenoid P-H insertion occurred in the thermocatalytic decomposition.

Keywords

Dimethyl Photolysis Benzophenone Thermal Reaction Direct Photolysis 

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Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • B. A. Arbuzov
    • 1
  • A. M. Polozov
    • 1
  • N. A. Polezhaeva
    • 1
  • A. Kh. Mustafin
    • 1
  • Ya. A. Levin
    • 1
  • É. I. Gol'dfarb
    • 1
  1. 1.A. M. Butlerov Institute of ChemistryV. I. Ul'yanov-Lenin Kazan State UniversityUSSR

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