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Effect of the acidity of phenols on the stereochemistry and stability of complexes extracted by butyl acetate

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Strengthening of extracted complexes with butyl acetate occurs with increasing phenol acidity. The stepwise formation constant of the disolvate from the monosolvate increases to a greater extent than the formation constant of the monosolvate, which leads to a change in the stoichiometry of the solvates formed.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Science Center, Urals Branch, Academy of Sciences of the USSR, Ufa

    E. L. Stol'skaya & N. L. Egutkin

Authors
  1. E. L. Stol'skaya
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  2. N. L. Egutkin
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 719–721, March, 1989.

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Stol'skaya, E.L., Egutkin, N.L. Effect of the acidity of phenols on the stereochemistry and stability of complexes extracted by butyl acetate. Russ Chem Bull 38, 645–647 (1989). https://doi.org/10.1007/BF00958069

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  • DOI: https://doi.org/10.1007/BF00958069

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