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Organoboron compounds and mass spectrometric study of derivatives of 2-amino- and 2-oxy-1,2-azaboroline

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Decomposition under the influence of electron impact of 2-organyl-1,2-azaborolines (I)–(XIII) occurs selectively, in the mass spectra an intense peak of the [M-R4]+ ion dominates, explained by the loss of the substituent from C3, the remaining ions usually do not exceed 10% of its intensity.

  2. 2.

    The boron-containing ring in the bicyclic compounds (III)–(XIII) is more stable to the influence of electron impact.

  3. 3.

    Fragmentation with rupture of the C-O bond in the alkyloxy group on the boron atom is characteristic for 2-alkoxy-1,2-azaborolines.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. S. Bleshinskaya, O. G. Boldyreva, B. M. Zolotarev, V. A. Dorokhov, O. S. Chizhov & B. M. Mikhailov

Authors
  1. A. S. Bleshinskaya
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  2. O. G. Boldyreva
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  3. B. M. Zolotarev
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  4. V. A. Dorokhov
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  5. O. S. Chizhov
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  6. B. M. Mikhailov
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Additional information

Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 587–593, March 1989.

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Bleshinskaya, A.S., Boldyreva, O.G., Zolotarev, B.M. et al. Organoboron compounds and mass spectrometric study of derivatives of 2-amino- and 2-oxy-1,2-azaboroline. Russ Chem Bull 38, 517–522 (1989). https://doi.org/10.1007/BF00958043

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  • DOI: https://doi.org/10.1007/BF00958043

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