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Negative ion mass spectrometry of substituted spiro[cyclopropan-1,1-indene]-2-carboxylates and 1-alkylideneindenes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The stability of MNI of substituted spiro[cyclopropan-1,1-indene]-2-carboxylates is increased with increasing π-system and introduction of electron acceptor substituents. The fragmentation of MNI is related to loss of substituents and is accompanied by opening of the cyclopropane ring.

  2. 2.

    The average lifetime of (M-R1,2) ions is measured relative to dissociation with elimination of a molecule of ethanol.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Scientific Center, Ural' Branch, Academy of Sciences of the USSR, Ufa

    V. K. Mavrodiev, I. I. Furlei, E. A. Burmistrov, F. Z. Galin, S. N. Lakeev, V. K. Ignatyuk & G. A. Tolstikov

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  1. V. K. Mavrodiev
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  2. I. I. Furlei
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  3. E. A. Burmistrov
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  4. F. Z. Galin
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  5. S. N. Lakeev
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  6. V. K. Ignatyuk
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  7. G. A. Tolstikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 576–580, March 1989.

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Mavrodiev, V.K., Furlei, I.I., Burmistrov, E.A. et al. Negative ion mass spectrometry of substituted spiro[cyclopropan-1,1-indene]-2-carboxylates and 1-alkylideneindenes. Russ Chem Bull 38, 507–511 (1989). https://doi.org/10.1007/BF00958041

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  • DOI: https://doi.org/10.1007/BF00958041

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