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Water-gas shift reaction in the liquid phase: Catalysis by water-soluble rhodium complexes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A series of water-soluble rhodium complexes containing diphenyl-m-sulfophenylphosphine as ligand are synthesized. The catalytic activity of the synthesized complexes in the WGSR is studied.

  2. 2.

    Probable mechanistic schemes for the WGSR are proposed, including intermediates not containing halide ions.

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Authors and Affiliations

  1. Institute of Structural Macrokinetics and Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR

    E. G. Chepaikin, A. P. Bezruchenko, E. N. Sal'nikova, F. Io, Z. Tom, M. T. Beck & M. L. Khidekel'

  2. Lajos Kossuth Univeristy, Debrecen, Hungary

    E. G. Chepaikin, A. P. Bezruchenko, E. N. Sal'nikova, F. Io, Z. Tom, M. T. Beck & M. L. Khidekel'

Authors
  1. E. G. Chepaikin
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  2. A. P. Bezruchenko
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  3. E. N. Sal'nikova
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  4. F. Io
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  5. Z. Tom
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  6. M. T. Beck
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  7. M. L. Khidekel'
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 542–549, March, 1989.

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Chepaikin, E.G., Bezruchenko, A.P., Sal'nikova, E.N. et al. Water-gas shift reaction in the liquid phase: Catalysis by water-soluble rhodium complexes. Russ Chem Bull 38, 476–482 (1989). https://doi.org/10.1007/BF00958036

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  • DOI: https://doi.org/10.1007/BF00958036

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