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Gas-phase deuterium exchange of fluorenes, furans, and thiophenes in the inlet system of a gas chromatograph/mass spectrometer

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Reaction columns containing a packing of KOD or D3PO4 in a stationary liquid phase on a support as components in a gas chromatograph/mass spectrometer were shown to provide selective basic H/D exchange of fluorenes and furans and acidic H/D exchange of thiophenes under gas-phase conditions. Such columns were proposed for use in the study of fragmentation mechanisms and establishment of the position of substituents in the ring.

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Literature cited

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    A. I. Mikaya, G. D. Romanov & V. G. Zaikin

Authors
  1. A. I. Mikaya
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  2. G. D. Romanov
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  3. V. G. Zaikin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 739–740, March, 1991.

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Mikaya, A.I., Romanov, G.D. & Zaikin, V.G. Gas-phase deuterium exchange of fluorenes, furans, and thiophenes in the inlet system of a gas chromatograph/mass spectrometer. Russ Chem Bull 40, 653–654 (1991). https://doi.org/10.1007/BF00958015

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  • DOI: https://doi.org/10.1007/BF00958015

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