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15N and13C NMR spectral study of the Z, E isomerism of thiophene aldoximes

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Abstract

Chemical shifts and coupling constants were determined in the15N and13C NMR spectra of thiophene aldoximes with natural isotope content. The effects of Z, E isomerism on the spectral parameters were determined. The2J15N.H and1J13C.H coupling constants in the CH=NOH fragment are characteristic.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. S. Bogdanov, B. I. Ugrak, M. A. Kalik, V. K. Zav'yalova & M. M. Krayushkin

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  1. V. S. Bogdanov
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  2. B. I. Ugrak
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  3. M. A. Kalik
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  4. V. K. Zav'yalova
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  5. M. M. Krayushkin
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 735–738, March, 1991.

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Bogdanov, V.S., Ugrak, B.I., Kalik, M.A. et al. 15N and13C NMR spectral study of the Z, E isomerism of thiophene aldoximes. Russ Chem Bull 40, 649–652 (1991). https://doi.org/10.1007/BF00958014

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  • DOI: https://doi.org/10.1007/BF00958014

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