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Magnetic and electric anisotropy of the P=O and P=S bonds relative to the Cotton-Mouton and Kerr effects

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

The Cotton-Mouton and Kerr effects were used to determine the molecular magnetic and electric anisotropies of the hexamethyl triamides of phosphorous, phosphoric, and thiophosphoric acids. The anisotropies of the phosphoryl and thiophosphoryl groups were calculated. The magnetic anisotropies of these bonds depend on the immediate environment at the phosphorus atom and correlate linearly with theσ P reactivity constant.

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Literature cited

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    S. G. Vul'fson, N. N. Sarvarova & O. N. Nuretdinova

Authors
  1. S. G. Vul'fson
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  2. N. N. Sarvarova
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  3. O. N. Nuretdinova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 733–735, March, 1991.

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Vul'fson, S.G., Sarvarova, N.N. & Nuretdinova, O.N. Magnetic and electric anisotropy of the P=O and P=S bonds relative to the Cotton-Mouton and Kerr effects. Russ Chem Bull 40, 647–649 (1991). https://doi.org/10.1007/BF00958013

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  • DOI: https://doi.org/10.1007/BF00958013

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