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ESR spectra of spin-adducts of hydroxyalkyl radicals with perfluoro-4-methyl-2-pentene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

A study was carried out on the ESR spectra of the spin-adducts of hydroxyalkyl radicals with perfluoro-4-methyl-2-pentene (I) formed upon the photolysis of alcoholic solutions of this perfluoroolefin. The stable conformational positions of the substituents in the spin-adducts depend on the structure of the hydroxyalkyl radicals. The spin-adducts are annihilated as a consequence of hydrogen atom abstraction as indicated in a preparative experiment.

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Literature cited

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organometallic Compounds, Academy of Sciences of the USSR, Moscow

    B. L. Tumanskii, M. A. Kurykin, S. P. Solodovnikov, N. N. Bubnov & L. S. German

Authors
  1. B. L. Tumanskii
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  2. M. A. Kurykin
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  3. S. P. Solodovnikov
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  4. N. N. Bubnov
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  5. L. S. German
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 730–732, March, 1991.

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Tumanskii, B.L., Kurykin, M.A., Solodovnikov, S.P. et al. ESR spectra of spin-adducts of hydroxyalkyl radicals with perfluoro-4-methyl-2-pentene. Russ Chem Bull 40, 644–646 (1991). https://doi.org/10.1007/BF00958012

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  • DOI: https://doi.org/10.1007/BF00958012

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