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Transformed steroids. 184. Pathways for the use of 17α-pregna-4,9-dien-3-on-17Β-ol-20-yne in the synthesis of 9, 11-disubstituted pregnanes

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

A study was carried out on pathways for the conversion of 17α-pregna-4, 9-dien-3-on-17Β-ol-20-yne to 9ξ, 11ξ-epoxypregn-4-en-17α-ol-3-on-20-ynes and their δ16− and 16α, 17α-epoxy derivatives, which are valuable intermediates in reported schemes for the synthesis of corticosteroids.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. M. Turuta, T. M. Fadeeva, A. V. Kamernitskii & Lyu Dyk Hu

Authors
  1. A. M. Turuta
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  2. T. M. Fadeeva
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  3. A. V. Kamernitskii
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  4. Lyu Dyk Hu
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 724–729, March, 1991.

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Turuta, A.M., Fadeeva, T.M., Kamernitskii, A.V. et al. Transformed steroids. 184. Pathways for the use of 17α-pregna-4,9-dien-3-on-17Β-ol-20-yne in the synthesis of 9, 11-disubstituted pregnanes. Russ Chem Bull 40, 638–643 (1991). https://doi.org/10.1007/BF00958011

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  • DOI: https://doi.org/10.1007/BF00958011

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