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Synthesis and several properties of 1, 3, 2, 5-dioxaboraphosphorinanes with a branched substituent at the boron atom

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Bis(α-hydroxyalkyl) phenylphosphines react with α-iminoboranes in protic solvents such as dihydric alcohols to give 2-(l′,1′-dibutylamyl)-4,6-di-R-5-phenyl-1, 3, 2, 5-dioxaboraphosphorinanes, which react with CuI in pyridine to form [LCuI(Py)] complexes. PMR spectroscopy showed that the phosphorus-containing ligands exist as a single stereoisomer.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    A. A. Karasik, G. N. Nikonov, B. A. Arbuzov, R. Z. Musin & Yu. Ya. Efremov

Authors
  1. A. A. Karasik
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  2. G. N. Nikonov
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  3. B. A. Arbuzov
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  4. R. Z. Musin
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  5. Yu. Ya. Efremov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 719–723, March, 1991.

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Karasik, A.A., Nikonov, G.N., Arbuzov, B.A. et al. Synthesis and several properties of 1, 3, 2, 5-dioxaboraphosphorinanes with a branched substituent at the boron atom. Russ Chem Bull 40, 633–637 (1991). https://doi.org/10.1007/BF00958010

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  • DOI: https://doi.org/10.1007/BF00958010

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