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1-Trifluoromethyl-2-chloroethylthiolated carbonyl compounds: Synthesis and properties

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

1-Trifluoromethyl-2-chloroethylsulfenyl chloride thiolates enolizible ketones, forming products of mono- and disubstitution. The properties of the resultant sulfides are determined by the presence in the molecule of two acidic CH centers. Thus, bromination proceeds at the ambident center and reaction with bases leads to (1-trifluoromethylvinyl) sulfides which are able to undergo intramolecular cyclizations and Diels-Alder reactions.

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Literature cited

  1. H. Bayreuther and A. Haas, Chem. Ber.,106, 1418 (1973).

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  2. A. Kolasa, J. Fluorine Chem.,36, 29 (1987).

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. Yu. Sizov, A. F. Kolomiets & A. V. Fokin

Authors
  1. A. Yu. Sizov
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  2. A. F. Kolomiets
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  3. A. V. Fokin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 676–681, March, 1991.

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Sizov, A.Y., Kolomiets, A.F. & Fokin, A.V. 1-Trifluoromethyl-2-chloroethylthiolated carbonyl compounds: Synthesis and properties. Russ Chem Bull 40, 592–596 (1991). https://doi.org/10.1007/BF00958002

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  • DOI: https://doi.org/10.1007/BF00958002

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