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Reactivity of 2-diethylaminomethylphenol and its copper(II) complex in the reaction with 4-nitrophenylbis(chloromethyl)-phosphinate

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

The kinetics of reactions of 2-diethylaminomethylphenol (I) and its Cu2+ complex (with a metal: ligand composition of 1∶2) (II) with 4-nitrophenylbis(chloromethyl)-phosphinate have been studied in aqueous-ethanolic media (10–70 vol. % ethanol); bimolecular rate constants have been calculated for the reactions of different forms of compound (I) and complex (II). It was shown that compound (I) in aqueous-ethanolic media is a nucleophilic catalyst for hydrolysis of 4-nitrophenylbis (chloromethyl)-phosphinate. The reactivity of complex (II) is an order of magnitude greater than that of the zwitterion form of the ligand which exists in the same range of pH 7–9.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    I. S. Ryzhkina, L. A. Kudryavtseva, V. E. Bel'skii & B. E. Ivanov

Authors
  1. I. S. Ryzhkina
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  2. L. A. Kudryavtseva
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  3. V. E. Bel'skii
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  4. B. E. Ivanov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 555–560, March, 1991.

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Ryzhkina, I.S., Kudryavtseva, L.A., Bel'skii, V.E. et al. Reactivity of 2-diethylaminomethylphenol and its copper(II) complex in the reaction with 4-nitrophenylbis(chloromethyl)-phosphinate. Russ Chem Bull 40, 478–482 (1991). https://doi.org/10.1007/BF00957979

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  • DOI: https://doi.org/10.1007/BF00957979

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