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Synthesis of (2-furyl)-β-alkylacetaldehydes by the hydroformylation of 2-alkenylfurans

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

A study was carried out on the hydroformylation of 2-vinyl- and 2-propenylfurans in the presence of HRh(CO)(PPh3)3 as a homogeneous catalyst. The substrate/ catalyst mole ratio was 600. Gas-liquid chromatography, PMR, and13C NMR spectroscopy were used to establish that the reaction proceeds regiosélectively in the case of 2-vinylfuran and regiospecifically in the case of 2-propenylfuran.

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Literature cited

  1. N. S. Zefirov, Yu. K. Yur'ev, V. M. Shteiman, and V. M. Gurevich, Abstracts of the First All-Union Inter-University Conference on the Chemistry of Furan Compounds [in Russian], Saratov (1959), p. 25.

  2. Yu. K. Yur'ev, N. S. Zefirov, and P. V. Kostetskii, Abstracts of the Second All-Union Conference on the Chemistry of Furan Compounds [in Russian], Saratov (1962), p. 30.

  3. G. Bauer, Inorganic Synthesis Handbook [Russian translation], Vol. 6, Mir, Moscow (1986), p. 2086.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. L. Lapidus, A. P. Rodin, I. G. Pruidze & B. I. Ugrak

Authors
  1. A. L. Lapidus
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  2. A. P. Rodin
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  3. I. G. Pruidze
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  4. B. I. Ugrak
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1661–1662, July, 1990.

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Lapidus, A.L., Rodin, A.P., Pruidze, I.G. et al. Synthesis of (2-furyl)-β-alkylacetaldehydes by the hydroformylation of 2-alkenylfurans. Russ Chem Bull 39, 1509–1511 (1990). https://doi.org/10.1007/BF00957876

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  • DOI: https://doi.org/10.1007/BF00957876

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