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Reaction of pentafluoro-2-azapropene withβ,γ-unsaturated alcohols

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Pentafluoro-2-azapropene reacts vigorously with β,γ-unsaturated alcohols in the presence of bases to give either the corresponding N-trifluoromethylcarbamates or the products of the vinyl substitution of the fluorine atoms at the azomethine bond. The intermediate azanions do not undergo [3,3]-sigmatropic rearrangement to give perfluoro-2-azapropenyl ethers.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. G. Andreev, A. F. Kolomiets & G. A. Sokol'skii

Authors
  1. V. G. Andreev
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  2. A. F. Kolomiets
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  3. G. A. Sokol'skii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1643–1645, July, 1990.

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Andreev, V.G., Kolomiets, A.F. & Sokol'skii, G.A. Reaction of pentafluoro-2-azapropene withβ,γ-unsaturated alcohols. Russ Chem Bull 39, 1493–1495 (1990). https://doi.org/10.1007/BF00957869

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  • DOI: https://doi.org/10.1007/BF00957869

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