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New conversions of substituted vinylcyclopropanes under the effect of complexes of rhodium and palladium

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Methods have been developed for the synthesis of the dimethyl ester of 1-carboxysorbic acid, 2-methyl-3-acetyl-5-vinyl- and 2-methyl-3-ethylcarboxy-5-vinyldihydrofurans by isomerization, respectively, of 1,1-dimethylcarboxy-2-vinyl-,1,1-diacetyl-2-vinyl-, and 1-acetyl-1-ethylcarboxy-2-vinylcyclo-propanes under the effect of Rh- and Pd-containing catalysts promoted with AcOH or CF3COOH.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Science Center, Ural Branch, Academy of Sciences of the USSR, Ufa

    U. M. Dzhemilev, R. I. Khusnutdinov, N. A. Shchadneva & G. A. Tolstikov

Authors
  1. U. M. Dzhemilev
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  2. R. I. Khusnutdinov
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  3. N. A. Shchadneva
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  4. G. A. Tolstikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1598–1601, July, 1990.

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Dzhemilev, U.M., Khusnutdinov, R.I., Shchadneva, N.A. et al. New conversions of substituted vinylcyclopropanes under the effect of complexes of rhodium and palladium. Russ Chem Bull 39, 1447–1450 (1990). https://doi.org/10.1007/BF00957856

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  • DOI: https://doi.org/10.1007/BF00957856

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