Skip to main content
SpringerLink
Log in

UV Absorption spectra of charge-transfer complexes of iodine with some derivatives of epoxycyclohexane and of glycidyl ether

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

UV spectroscopy has been used to study the relative donor power of some derivatives of epoxycyclohexane and of glycidyl ether in the formation of charge-transfer complexes (CTC) with iodine. It is shown that the introduction of a second epoxycyclohexane fragment into the molecule of a substituted 1,2-epoxycyclohexane considerably increases the stability of complexes with molecular iodine, and that the donor power of aromatic derivatives of glycidyl ether considerably exceeds that of their structural analogs, derivatives of anisole.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. V. N. Kokorev, N. N. Vyshinskii, V. P. Maslennikov, et al., Zh. Strukt. Khim.,23, No. 6, 14 (1982).

    Google Scholar 

  2. V. V. Voronenkov, Yu. G. Osokin, V. N. Baidin, et al., Neftekhimiya,25, No. 2, 234 (1985).

    Google Scholar 

  3. G. V. Belysheva, A. N. Egorochkin, V. V. Voronenkov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 6, 1314 (1990).

    Google Scholar 

  4. A. A. Blagonravova and A. I. Nepomnyashchii, Varnish Epoxy Resins [in Russian], Izd. Khimiya, Moscow (1970).

    Google Scholar 

  5. A. M. Paken, Epoxy Compounds and Epoxy Resins [in Russian], Goskhimizdat, Leningrad, 1962.

    Google Scholar 

  6. G. Briegleb, Electronen-Donator-Acceptor-Komplexe, Springer, Berlin, N.Y., 1961.

    Google Scholar 

  7. S. M. Brandon, M. Tamres, and S. Searles, J. Am. Chem. Soc,82, 2129 (1960).

    Google Scholar 

  8. I. G. Gazizov and G. A. Chutova, Zh. Obshch. Khim.,50, 2063 (1980).

    Google Scholar 

  9. A. J. Gordon and R. A. Ford, A Chemist's Companion, Wiley, New York (1973).

    Google Scholar 

  10. A. E. Batog, O. P. Stenko, and L. P. Nikonova, Zh. Org. Khim.,16, 1126 (1980).

    Google Scholar 

  11. H. Benesi and J. H. Hildebrand, J. Am. Chem. Soc,70, 2832 (1948).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute for Organometallic Chemistry, Academy of Sciences of the USSR, Gor'kii

    G. V. Belysheva, O. N. Karpov, M. A. Lopatin, P. G. Sennikov & A. N. Egorochkin

Authors
  1. G. V. Belysheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. N. Karpov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. A. Lopatin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. G. Sennikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. N. Egorochkin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1574–1577, July, 1990.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Belysheva, G.V., Karpov, O.N., Lopatin, M.A. et al. UV Absorption spectra of charge-transfer complexes of iodine with some derivatives of epoxycyclohexane and of glycidyl ether. Russ Chem Bull 39, 1425–1427 (1990). https://doi.org/10.1007/BF00957852

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00957852

Keywords

Search

Navigation