Abstract
Trans-3-methylthiocaran-4-one was synthesized. Its structure was established by x-ray structural analysis. The dipole moment was determined. The molar Kerr constants were measured, and the dipole moments were determined, for α-methylthioacetone and α-methylthiocyclohexanone. It was found that the lowpolar gauche conformer at the C-S bond is realized in all cases for the acstate at the C-C(O) bond in the methylthiocarbonyl fragment.
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Deceased.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1563–1569, July, 1990.
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Kazakova, É.K., Davletshina, G.R., Vereshchagin, A.N. et al. Conformational investigation of α-methylthio-substituted acetone, cyclohexanone, and caran-4-one. Russ Chem Bull 39, 1414–1420 (1990). https://doi.org/10.1007/BF00957850
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DOI: https://doi.org/10.1007/BF00957850