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Mass spectra of the hydrogenated products of condensation of 1,3-cyclohexadiene and bicyclo[2.2.2]octene and their aromatic analogs

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

The structures of completely hydrogenated and aromatized products of the reaction of bicyclo[2.2.2]octene and 1,3-cyclohexadiene were investigated by mass spectrometry. It is shown that the reaction proceeds via mechanisms of the linear polymerization type and the Diels-Alder polymerization type; hydrocarbons, the molecules of which include bridged, condensed, interlinked, and mixed types of ring fusion, are formed.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1549–1553, July, 1990.

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Golovkina, L.S., Vorob'eva, N.S., Zemskova, Z.K. et al. Mass spectra of the hydrogenated products of condensation of 1,3-cyclohexadiene and bicyclo[2.2.2]octene and their aromatic analogs. Russ Chem Bull 39, 1402–1405 (1990). https://doi.org/10.1007/BF00957847

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  • DOI: https://doi.org/10.1007/BF00957847

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