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Reaction of stannous bis-3,6-di-tert-butyl-o-semiquinolate with phenoxyl radicals

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

An EPR study was carried out on the reaction of stannous bis-3,6-di-tert-butyl-o-semiquinolate with several phenoxyl radicals. An oxidative addition reaction may proceed with the formation of radicals with stannic ions. The reaction of biradical stannous complexes with 3,6-di-tert-butyl-2-hydroxyphenoxyl in the presence of triphenylphosphine in toluene gave a tin-containing free radical. The EPR spectra of this radical indicated rapid interligand exchange of the unpaired electron and bond.

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Authors and Affiliations

  1. V. V. Nikitin Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe

    R. R. Rakhimov, P. M. Solozhenkin, V. S. Pupkov & A. I. Prokof'ev

  2. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    R. R. Rakhimov, P. M. Solozhenkin, V. S. Pupkov & A. I. Prokof'ev

Authors
  1. R. R. Rakhimov
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  2. P. M. Solozhenkin
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  3. V. S. Pupkov
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  4. A. I. Prokof'ev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1532–1535, July, 1990.

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Rakhimov, R.R., Solozhenkin, P.M., Pupkov, V.S. et al. Reaction of stannous bis-3,6-di-tert-butyl-o-semiquinolate with phenoxyl radicals. Russ Chem Bull 39, 1385–1387 (1990). https://doi.org/10.1007/BF00957843

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  • DOI: https://doi.org/10.1007/BF00957843

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