Skip to main content
SpringerLink
Log in

Synthesis and photochromic properties of spiroanthrooxazine

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

1′,3′,3′-Trimethylspiro[indoline-2′,3-3H-anthraceno[2,1-b][1,4]oxazine] was synthesized. The compound has photochromic properties in solutions and in polymeric matrices. It was found from the spectral data that the colored form of the spiroanthrooxazine exists in a quinoid form and is characterized by a positive solvatochromic effect.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. V. S. Marevtsev, L. S. Kol'tsova, A. V. Lyubimov, and M. I. Cherkashin, Izv. Akad. Nauk SSSR, Ser. Khim., No. 10, 2259 (1988).

    Google Scholar 

  2. N. L. Zaichenko, A. V. Lyubimov, V. S. Marevtsev, and M. I. Cherkashin, Izv. Akad. Nauk SSSR, Ser. Khim., No. 5, 1040 (1989).

    Google Scholar 

  3. V. Yu. Nedoshivin, A. V. Lyubimov, N. L. Zaichenko, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 11, 2576 (1989).

    Google Scholar 

  4. A. G. Ovcharenko, A. V. Lyubimov, V. Yu. Nedoshivin, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 3, 543 (1990).

    Google Scholar 

  5. K. Lauer, J. Prakt. Chem.,135, 173 (1932).

    Google Scholar 

  6. C. Lieberman, Liebigs Ann. Chem.,212, 1 (1882).

    Google Scholar 

  7. K. Lagodzinski, Liebigs Ann. Chem.,342, 59 (1905).

    Google Scholar 

  8. M. V. Gorelik and T. A. Mikhailova, Zh. Obshch. Khim.,34, No. 6, 1997 (1964).

    Google Scholar 

  9. U.-W. Grummt, M. Reichenbächer, and R. Paetzold, Tetrahedron Lett.,22, No. 40, 3945 (1981).

    Google Scholar 

  10. R. C. Bertelson, Photochromism (Techn. Chem.), Vol. 3, G. H. Brown (ed.), Wiley, New York (1971).

    Google Scholar 

  11. N. Y. C. Chu, Can. J. Chem.,61, No. 2, 300 (1983).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    T. Ya. Vlasenko, N. L. Zaichenko, A. V. Lyubimov, V. S. Marevtsev & M. I. Cherkashin

Authors
  1. T. Ya. Vlasenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. L. Zaichenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Lyubimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. S. Marevtsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. I. Cherkashin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1521–1525, July, 1990.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vlasenko, T.Y., Zaichenko, N.L., Lyubimov, A.V. et al. Synthesis and photochromic properties of spiroanthrooxazine. Russ Chem Bull 39, 1375–1379 (1990). https://doi.org/10.1007/BF00957841

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00957841

Keywords

Search

Navigation