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Correlation between the stereochemistry and optical activity of chiral dimolybdenum tetracarboxylates and related compounds

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Sector rules for chiral dimolybdenum tetracarboxylates and related compounds were derived using the “one-electron model” of optical activity. The correlation between the sign of the Cotton effect (CE) of the δ→δ* transition and the stereochemistry of this type of binuclear clusters is expressed as a rule of 16 in which the positive sign of the EC corresponds to the negative sign of the pseudoscalar function xyz(x2-y2) of the cluster atoms. A negative sign of the CE was predicted for the δ→δ* transition in cis-(L-isoleucine)2(NCS)4Mo2.

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Literature cited

  1. P. A. Agaskar, F. A. Cotton, I. F. Fraser, et al., Inorg. Chem.,25, 2511 (1986).

    Google Scholar 

  2. R. D. Peacock, Polyhedron,6, 715 (1987).

    Google Scholar 

  3. G. Snatzke, U. Wagner, and H. P. Wolf, Tetrahedron,37, 349 (1981).

    Google Scholar 

  4. J. Frelek, A. Perkowska, G. Snatzke, et al., Spectrosc. Int. J.,2, 274 (1983).

    Google Scholar 

  5. A. P. Klyagina and I. F. Golovaneva, Dokl. Akad. Nauk SSSR,298, 138 (1988).

    Google Scholar 

  6. F. A. Cotton, L. R. Falvello, and C. A. Murillo, Inorg. Chem.,22, 382 (1983).

    Google Scholar 

  7. J. A. Schellman, J. Chem. Phys.,44, 55 (1966).

    Google Scholar 

  8. F. A. Cotton, Polyhedron,5, 3 (1986).

    Google Scholar 

  9. F. A. Cotton and R. A. Walton, Multiple Bonds Between Metal Atoms, Wiley, New York (1982).

    Google Scholar 

  10. A. Bino and F. A. Cotton, Inorg. Chem.,18, 1381 (1979).

    Google Scholar 

  11. A. Bino, F. A. Cotton, and P. E. Fanwick, Inorg. Chem.,19, 1215 (1980).

    Google Scholar 

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    A. P. Klyagina, I. F. Golovaneva & G. G. Sadikov

Authors
  1. A. P. Klyagina
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  2. I. F. Golovaneva
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  3. G. G. Sadikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1504–1507, July, 1990.

We would like to thank M. A. Porai-Koshits and A. A. Levin for becoming acquainted with the research and discussing the results obtained.

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Klyagina, A.P., Golovaneva, I.F. & Sadikov, G.G. Correlation between the stereochemistry and optical activity of chiral dimolybdenum tetracarboxylates and related compounds. Russ Chem Bull 39, 1360–1362 (1990). https://doi.org/10.1007/BF00957838

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  • DOI: https://doi.org/10.1007/BF00957838

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