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Effect of the structure of the aromatic system on the rate of dimerization of radical anions of aromatic nitro compounds

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

The radical anions formed in the first stage of electrolytic reduction of 9-nitroanthracene, 1-nitronaphthalene, and nitrobenzene enter into a secondorder reaction in which the value of the rate constant increases as the degree of localization of the unpaired electron on the reaction site increases.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. S. Mendkovich, A. P. Churilina, L. V. Mikhal'chenko & V. P. Gul'tyai

Authors
  1. A. S. Mendkovich
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  2. A. P. Churilina
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  3. L. V. Mikhal'chenko
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  4. V. P. Gul'tyai
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1492–1495, July, 1990.

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Mendkovich, A.S., Churilina, A.P., Mikhal'chenko, L.V. et al. Effect of the structure of the aromatic system on the rate of dimerization of radical anions of aromatic nitro compounds. Russ Chem Bull 39, 1348–1351 (1990). https://doi.org/10.1007/BF00957835

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  • DOI: https://doi.org/10.1007/BF00957835

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