Reactions of strained hydrocarbons in the presence of platinum carboxylate complexes

  • N. F. Gol'dshleger
  • S. A. Filimonov
  • M. L. Khidekel'
Brief Communications

Conclusions

  1. 1.

    Bicyclo[2.2.1]hepta-2,5-diene dimerizes in the presence of Pt(III) acetate and trifluoroacetate, and also Pt(II) trifluoroacetate, to give [2 +2]-cycloaddition products, and specifically the exo-trans-exo- and exo-transendo-pentacyclo[8.2.1.14,702,909,8]tetradeca-5,11-dienes.

     
  2. 2.

    Pt(II) trifluoroacetate actively catalyzes the valence isomerization of the quadricyclane in norbornadiene.

     

Keywords

Acetate Platinum Hydrocarbon Carboxylate Diene 

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Copyright information

© Plenum Publishing Corporation 1983

Authors and Affiliations

  • N. F. Gol'dshleger
    • 1
  • S. A. Filimonov
    • 1
  • M. L. Khidekel'
    • 1
  1. 1.Branch of Institute of Chemical PhysicsAcademy of Sciences of the USSRChernogolovka

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