Polarity and polarizability of polychloroalkyl derivatives of amides

  • A. N. Vereshchagin
  • D. M. Nasyrov
Physical Chemistry
  • 14 Downloads

Conclusions

  1. 1.

    The parameters of the polarizability ellipsoid of the trichloroacetamide group were determined.

     
  2. 2.

    Dichloroacetamide in dioxane is in the form of an equilibrium mixture of conformers with predominance of the less polar conformer.

     
  3. 3.

    A structure with a gauche-gauche conformation of the Cl-C-N-C-Cl chain is most probable for N,N-di(chloromethyl)trichloroacetamide.

     

Keywords

Amide Dioxane Chloromethyl Equilibrium Mixture Polarizability Ellipsoid 

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Copyright information

© Plenum Publishing Corporation 1983

Authors and Affiliations

  • A. N. Vereshchagin
    • 1
  • D. M. Nasyrov
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryKazan Branch of the Academy of Sciences of the USSRUSSR

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