Conclusions
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1.
The parameters of the polarizability ellipsoid of the trichloroacetamide group were determined.
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2.
Dichloroacetamide in dioxane is in the form of an equilibrium mixture of conformers with predominance of the less polar conformer.
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3.
A structure with a gauche-gauche conformation of the Cl-C-N-C-Cl chain is most probable for N,N-di(chloromethyl)trichloroacetamide.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2704–2708, December, 1982.
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Vereshchagin, A.N., Nasyrov, D.M. Polarity and polarizability of polychloroalkyl derivatives of amides. Russ Chem Bull 31, 2391–2394 (1982). https://doi.org/10.1007/BF00957703
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DOI: https://doi.org/10.1007/BF00957703