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Influence of electronic factors in reactivity on volume activation effect in Diels-Alder reactions

  • E. M. Vasil'vitskaya
  • B. S. Él'yanov
Physical Chemistry

Conclusions

  1. 1.

    The volume activation effect in forward and reverse Diels-Alder reactions does not depend on the electron-donor or electron-acceptor character of the substituent, nor on its strength or its position in the diene.

     
  2. 2.

    In the absence of significant solvation effects, the Hammettρ-constants of Diels-Alder reactions are independent of the pressure.

     
  3. 3.

    The probable volume profile of the reactions is discussed.

     

Keywords

Diene Activation Effect Solvation Effect Volume Activation Volume Profile 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1983

Authors and Affiliations

  • E. M. Vasil'vitskaya
    • 1
  • B. S. Él'yanov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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