Influence of electronic factors in reactivity on volume activation effect in Diels-Alder reactions

  • E. M. Vasil'vitskaya
  • B. S. Él'yanov
Physical Chemistry
  • 13 Downloads

Conclusions

  1. 1.

    The volume activation effect in forward and reverse Diels-Alder reactions does not depend on the electron-donor or electron-acceptor character of the substituent, nor on its strength or its position in the diene.

     
  2. 2.

    In the absence of significant solvation effects, the Hammettρ-constants of Diels-Alder reactions are independent of the pressure.

     
  3. 3.

    The probable volume profile of the reactions is discussed.

     

Keywords

Diene Activation Effect Solvation Effect Volume Activation Volume Profile 

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Copyright information

© Plenum Publishing Corporation 1983

Authors and Affiliations

  • E. M. Vasil'vitskaya
    • 1
  • B. S. Él'yanov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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