Formation of stable radicals upon the photolysis of perfluoro-2,4-dimethyl-3-ethyl-2-pentene
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The photolysis of liquid perfluoro-2,4-dimethyl-3-ethyl-2-pentene gives perfluoroallyl and perfluoroalkyl radicals with anomalously long lifetime in the liquid at room temperature. The accumulation and decomposition of perfluoroallyl radicals occurs in the initial stage of the photolysis. Accumulation of perfluoroalkyl radicals occurs upon more prolonged photolysis.
KeywordsPhotolysis Stable Radical Perfluoroalkyl Radical Perfluoroallyl Prolonged Photolysis
- 1.S. R. Allayarov, I. M. Barkalov, V. I. Gol'danskii, and D. P. Kiryukhin, Izv. Akad. Nauk Ser. Khim., 1225 (1983).Google Scholar
- 2.S. R. Allayarov, S. I. Kuzina, D. P. Kiryukhin, I. M. Barkalov, and A. I. Mikhailov, Khim. Vysok. Énerg., No. 1 (1986).Google Scholar
- 3.A. N. Bell and R. Fields, J. Chem. Soc., Perkin Trans, 1, 487 (1980).Google Scholar