Conclusion
The addition of 2-trichloromethyl-l,3-dioxolane to vinyltrimethylsilane upon initiation by a system consisting of Fe(CO)5 and a nucleophilic cocatalyst proceeds to cleavage of a C-Cl bond in the trichloromethyl group with the formation of an adduct containing the dioxolanyl ring.
Literature cited
R. Kh. Freidlina, F. K. Velichko, and A. B. Terent'ev, Usp. Khlm.,53, 370 (1984).
R. Kh. Freidlina, R. G. Gasanov, N. A. Kuz'mina, and E. Ts. Chukovskaya, Usp. Khim.,54, 1127 (1985).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2351–2353, October, 1986.
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Terent'ev, A.B., Makaeva, R.M. & Musavirov, R.S. Radical addition of 2-trichloromethyl-1,3-dioxolane to vinyltrimethylsilane. Russ Chem Bull 35, 2153–2155 (1986). https://doi.org/10.1007/BF00957550
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DOI: https://doi.org/10.1007/BF00957550