Conclusions
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1.
The formation of an iron porphyrin peroxo complex from molecular oxygen and a sterically hindered iron porphyrin was detected in the presence of zinc amalgam and methylviologen in acetonitrile.
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2.
The catalytic oxidation of cyclohexane was detected in this system was detected in the presence of Ac2O and a mechanism was proposed for this reaction.
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Literature cited
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2329–2330, October, 1986.
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Khenkin, A.M. A new pathway for the activation of molecular oxygen. Russ Chem Bull 35, 2131–2132 (1986). https://doi.org/10.1007/BF00957541
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DOI: https://doi.org/10.1007/BF00957541