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Synthesis of N′-methoxydiazene N-oxide derivatives of malonate and cyanoacetate esters

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

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A method of synthesis was proposed for alkoxydiazene oxide derivatives of malonic and cyanoacetic acids by the reaction of methyl (N'-methoxydiazene-N-oxido)acetate with sodium hydride and subsequent treatment with alkoxycarbonylating or cyanating reagents.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2322–2323, October, 1986.

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Varnaeva, G.N., Podgurskii, A.I., Zlotin, S.G. et al. Synthesis of N′-methoxydiazene N-oxide derivatives of malonate and cyanoacetate esters. Russ Chem Bull 35, 2125–2126 (1986). https://doi.org/10.1007/BF00957538

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  • DOI: https://doi.org/10.1007/BF00957538

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