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Asymmetrical nitrogen. 52. Nucleophilic substitution at nitrogen in N-chloro-N-alkoxyamines

  • V. F. Rudchenko
  • S. M. Ignatov
  • V. S. Nosova
  • I. I. Chervin
  • R. G. Kostyanovskii
Organic Chemistry
  • 29 Downloads

Conclusions

  1. 1.

    The reaction of methyl α-(N-chloro-N-methoxyamino)isobutyrate with pyridine in CD3CN is bimolecular.

     
  2. 2.

    The dimethyl ester of an NH-isoxazolidine-3,3-dicarboxylic acid and an optically active N-chloro-N-alkoxyamine [(+)-dimethyl N-chloroisoxazolidine-3,3-dicarboxylate] have been obtained for the first time. It has been shown that low-temperature methanolysis of the latter takes place with retention of optical activity.

     

Keywords

Nitrogen Methyl Ester Pyridine Dimethyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • V. F. Rudchenko
    • 1
  • S. M. Ignatov
    • 1
  • V. S. Nosova
    • 1
  • I. I. Chervin
    • 1
  • R. G. Kostyanovskii
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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