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Formation of 1,3-dimethyladamantane from cis, trans, trans-1,5,9-cyclododecatriene

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    During isomerization of cis, trans, trans-l,5,9-cyclododecatriene under the action of polyphosphoric acid mainly 1a,3,4,5,6,7,8,8a- and 2a,3,4,5,6,7,8-octahydroacenaphthenes are obtained, and under the action of i-Bu3Al formation of tricyclo[7.3.0.O2,6]dodecenes is observed. A new catalytic system Cp2TiCl2-i-Bu3Al is proposed for isomerization of the latter type.

  2. 2.

    Two new methods for obtaining 1,3-dimethyladamantane from cis,trans,trans-l,5,9-cyclododecatriene are proposed.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelemental Compounds, Academy of Sciences of the USSR, Moscow

    L. I. Zakharkin, G. G. Zhigareva, A. P. Pryanishnikov & S. T. Ovseenko

Authors
  1. L. I. Zakharkin
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  2. G. G. Zhigareva
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  3. A. P. Pryanishnikov
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  4. S. T. Ovseenko
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2256–2259, October, 1986.

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Zakharkin, L.I., Zhigareva, G.G., Pryanishnikov, A.P. et al. Formation of 1,3-dimethyladamantane from cis, trans, trans-1,5,9-cyclododecatriene. Russ Chem Bull 35, 2061–2064 (1986). https://doi.org/10.1007/BF00957524

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  • DOI: https://doi.org/10.1007/BF00957524

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