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Chemiluminescence testing of solutions to detect organometallic peroxides during oxidation of organometallic compounds by oxygen

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The possibility of detecting organometallic peroxides without decreasing the temperature and hydrolysis of the reaction solution during oxidation of organometallic compounds with oxygen based on the kinetic maxima of the intensity of chemiluminescence was demonstrated.

  2. 2.

    The formation of organometallic peroxides was detected during oxidation of organic derivatives of uranium and lanthanides with oxygen.

  3. 3.

    The stage of formation of an organometallic peroxide during oxidation of organometallic compounds with oxygen takes place more rapidly than the reactions of its subsequent consumption.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa

    R. G. Bulgakov, S. P. Kuleshov, V. N. Yakovlev, G. Ya. Maistrenko, G. A. Tolstikov & V. P. Kazakov

Authors
  1. R. G. Bulgakov
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  2. S. P. Kuleshov
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  3. V. N. Yakovlev
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  4. G. Ya. Maistrenko
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  5. G. A. Tolstikov
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  6. V. P. Kazakov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2216–2218, October, 1986.

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Bulgakov, R.G., Kuleshov, S.P., Yakovlev, V.N. et al. Chemiluminescence testing of solutions to detect organometallic peroxides during oxidation of organometallic compounds by oxygen. Russ Chem Bull 35, 2022–2024 (1986). https://doi.org/10.1007/BF00957515

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  • DOI: https://doi.org/10.1007/BF00957515

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