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Photogatalytic formation of a strong oxidant Os(bipy)3 3+ inside lipid vesicles with a high quantum yield

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Two photocatalytic systems for generation of a strong oxidant: the triple-charged tris-(2,2'-bipyridyl)osmium(III) cation [Os(bipy)3 3+] inside lipid bilayer vesicles were proposed.

  2. 2.

    The quantum yield of formation of Os(bipy)3 3+ inside the vesicles corresponds to the quantum yield of irreversible oxidation of the photosensitizer, which attains 30% in the optimum conditions.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR

    E. I. Knerel'man & V. A. Shafirovich

Authors
  1. E. I. Knerel'man
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  2. V. A. Shafirovich
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2213–2216, October, 1986.

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Knerel'man, E.I., Shafirovich, V.A. Photogatalytic formation of a strong oxidant Os(bipy)3 3+ inside lipid vesicles with a high quantum yield. Russ Chem Bull 35, 2019–2022 (1986). https://doi.org/10.1007/BF00957514

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  • DOI: https://doi.org/10.1007/BF00957514

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