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Effect of high pressure on the activation parameters of thermal transformations of trimethylsilyl(cumyl) peroxide in the liquid phase

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The activation parameters of thermal transformations of trimethylsilyl(cumyl) peroxide (I) in cumene in the 20–1000 MPa range were determined. It was found that the acceleration of the reaction by the pressure is due to a significant decrease in the activation energy with an increase in the pressure.

  2. 2.

    The total rate constant of the transformations of (I) in the range of high pressures is a function of the initial concentration of the peroxide.

  3. 3.

    The results obtained are in agreement with the hypothesized mechanism of transformations of (I), including the reaction of two molecules of the peroxide in the cyclic transition state in addition to a monomolecular reaction.

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Literature cited

  1. V. A. Yablokov, Usp. Khim.,49, 1711 (1980).

    Google Scholar 

  2. V. M. Zhulin, G. A. Stashina, A. V. Ganyushkin, N. V. Yablokova, V. A. Yablokov, and O. B. Rudakov, Izv. Akad. Nauk SSSR, Ser. Khim., 1659 (1983).

  3. V. M. Zhulin, O. B. Rudakov, G. A. Stashina, A. V. Ganyushkin, V. A. Yablokov, and N. N. Vainberg, Izv. Akad. Nauk SSSR, Ser. Khim., 1979 (1985).

  4. B. S. El'yanov and E. M. Vsilvitskaya, Rev. Phys. Chem. Jpn.,50, 169 (1980).

    Google Scholar 

  5. H. Tiltscher and Y. K. Wang, Z. Phys. Chem.,99, No. 4, 299 (1976).

    Google Scholar 

  6. J. Rimmelin and G. Jenner, Tetrahedron,30, 3081 (1974).

    Google Scholar 

  7. V. A. Yablokov, A. V. Ganyushkin, M. Ya. Botnikov, and V. M. Zhulin, Izv. Akad. Nauk SSSR, Ser. Khim., 950 (1980).

  8. M. Buback and H. Lendle, Z. Naturforsch.,34a, 1482 (1979).

    Google Scholar 

  9. V. A. Yablokov, A. N. Sunin, L. Ya. Isaeva, and N. I. Kostina, Zh. Obshch. Khim.,43, 1305 (1973).

    Google Scholar 

  10. V. A. Yablokov, A. N. Sunin, G. N. Saigina, and A. V. Ganyushkin, Zh. Obshch. Khim.,43, 1308 (1973).

    Google Scholar 

  11. V. A. Yablokov, A. V. Ganyushkin, and N. V. Yablokova, Zh. Obshch. Khim.,47, 2553 (1977).

    Google Scholar 

  12. R. R. Hiatt, Can. J. Chem.,42, 985 (1964).

    Google Scholar 

  13. Yu. A. Aleksandrov, V. V. Gorbatov, V. G. Tsvetkov, and N. V. Yablokova, Dokl. Akad. Nauk SSSR,234, 826 (1977).

    Google Scholar 

  14. N. P. Sluchevskaya, N. V. Yablokova, V. A. Yablokov, and Yu. A. Aleksandrov, Zh. Obshch. Khim.,48, 1136 (1978).

    Google Scholar 

  15. G. Jenner and J. Rimmelin, Tetrahedron Lett.,21, 3039 (1980).

    Google Scholar 

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. M. Zhulin, O. B. Rudakov, A. V. Ganyushkin & V. A. Yablokov

Authors
  1. V. M. Zhulin
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  2. O. B. Rudakov
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  3. A. V. Ganyushkin
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  4. V. A. Yablokov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2206–2212, October, 1986.

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Zhulin, V.M., Rudakov, O.B., Ganyushkin, A.V. et al. Effect of high pressure on the activation parameters of thermal transformations of trimethylsilyl(cumyl) peroxide in the liquid phase. Russ Chem Bull 35, 2013–2018 (1986). https://doi.org/10.1007/BF00957513

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  • DOI: https://doi.org/10.1007/BF00957513

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