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Electrochemical bromination of dmso in alkaline media: The synthesis of 1,1,1-tribromo- and hexabromodimethylsulfones

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The electrochemical bromination of DMSO in alkaline media leads to the formation of (CBr3)2SO2 (in the presence of Na2CO3) or CBr3SO2CH3 (in the presence of NaHCO3).

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Literature cited

  1. C. F. Bennett, D. W. Goheen, and W. S. McGregor, J. Org. Chem.,28, 2485 (1963).

    Google Scholar 

  2. H. Johnston, US Patent No. 3,051,757; Chem. Abstr.,58, 8908a (1963).

    Google Scholar 

  3. J. A. Reuterskioeld, J. Prakt. Chem.,129, 121 (1931).

    Google Scholar 

  4. S. Chidambaram, M. S. V. Pathy, and H. V. K. Udupa, Indian J. Chem.,5, 346 (1967).

    Google Scholar 

  5. W. E. Farrar, J. Chem. Soc., No. 3, 508 (1956).

    Google Scholar 

  6. B. G. Cox and A. Gibson, J. Chem. Soc, Perkin Trans. 2, No. 10, 1355 (1973).

    Google Scholar 

  7. W. E. Truce, G. H. Birum, and E. T. McBee, J. Am. Chem. Soc.,74, 2594 (1952).

    Google Scholar 

  8. F. Boberg, G. Winter, and G. Richard, Chem. Ber.,89, 1160 (1956).

    Google Scholar 

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 471–472, February, 1988.

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Ilyushin, V.A. Electrochemical bromination of dmso in alkaline media: The synthesis of 1,1,1-tribromo- and hexabromodimethylsulfones. Russ Chem Bull 37, 391–392 (1988). https://doi.org/10.1007/BF00957456

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  • DOI: https://doi.org/10.1007/BF00957456

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