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Z, E isomerization of alkoxypropenylphosphonium salts by the action of nucleophiles

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Heating Z-triphenyl(2-alkoxyprop-1-enyl)phosphonium iodides with diethylamine and triethylamine leads to their partial geometric isomerization.

  2. 2.

    Heating of these salts with alcohols leads to their exchange of the alkoxy group and partially reversible addition of the alcohol at the double bond in addition to isomerization.

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Authors and Affiliations

  1. M. V. Lonomosov Moscow State University, USSR

    Nik A. Nesmeyanov, V. G. Kharitonov, O. A. Rebrova, P. V. Petrovskii & O. A. Reutov

Authors
  1. Nik A. Nesmeyanov
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  2. V. G. Kharitonov
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  3. O. A. Rebrova
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  4. P. V. Petrovskii
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  5. O. A. Reutov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 456–459, February, 1988.

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Nesmeyanov, N.A., Kharitonov, V.G., Rebrova, O.A. et al. Z, E isomerization of alkoxypropenylphosphonium salts by the action of nucleophiles. Russ Chem Bull 37, 375–378 (1988). https://doi.org/10.1007/BF00957449

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  • DOI: https://doi.org/10.1007/BF00957449

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