Conclusions
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1.
The haptotropic rearrangements in the chromium tricarbonyl complexes of 1-methylacenaphthene take place predominantly with retention of the stereochemistry, i.e., the exo-and endo-configuration of the interconverting complexes is preserved during the rearrangement.
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2.
The mechanism of the rearrangements observed in the chromium tricarbonyl complexes of naphthene and its analogs was established. It involves intramolecular migration of the organometallic group betwen the six-membered rings.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 438–441, February, 1988.
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Oprunenko, Y.F., Malyugina, S.G., Trifonova, O.I. et al. Mechanism of haptotropic rearrangements in the chromium tricarbonyl complexes of naphthalene and its analogs. Russ Chem Bull 37, 357–360 (1988). https://doi.org/10.1007/BF00957445
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DOI: https://doi.org/10.1007/BF00957445