Direct metallation of cyclic conjugated hydrocarbons by highly reactive magnesium

  • U. M. Dzhemilev
  • A. G. Ibragimov
  • E. V. Gribanova
  • L. M. Khalilov
Organic Chemistry


Organomagnesium compounds have been prepared by the direct metallation of cyclopentadiene, indene, fluorene, and cyclooctatetraene and by highly reactive magnesium. Their crosscombination with allyl and propargyl electrophiles in the presence of metal complex catalysts has been studied, this leading to the allyl and propargyl substituted hydrocarbons being obtained in high yields.


Indene Magnesium Hydrocarbon Fluorene Metal Complex 
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Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • U. M. Dzhemilev
    • 1
  • A. G. Ibragimov
    • 1
  • E. V. Gribanova
    • 1
  • L. M. Khalilov
    • 1
  1. 1.Institute of Chemistry, Bashkir BranchAcademy of Sciences of the USSRUfa

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