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Conclusions

Perfluorotert-butyl iodide is formed in high yield upon pyrolysis of hexafluoropropylene with perfluoromethyl iodide. Perfluorotert-butyl iodide is also formed in low yield when perfluorotert-butyl bromide or chloroformate is treated with alkali metal iodides and also from bis(trifluoromethyl)diazirine and perfluoromethyl iodide.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 402–404, February, 1988.

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Deev, L.E., Nazarenko, T.I. & Pashkevich, K.I. New route to perfluorotert-butyl iodide. Russ Chem Bull 37, 321–323 (1988). https://doi.org/10.1007/BF00957435

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  • DOI: https://doi.org/10.1007/BF00957435

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