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Perfluorinated dioxolanes. 2. Reaction of perfluoro-4-oxo-1,3-dioxolanes with fluorine ion

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A new equilibrium reaction was found involving transformation of perfluoro-4-oxo-2,5-dimethyl-2-(2′-oxa-3′-fluorocarbonylbutyl)-1,3,-dioxolane into perfluoro-4-oxo-2,5-dimethyl-2-fluorocarbonyl-1, 3-dioxolane and perfluoro-2-oxo-3,6-dimethyl-1,4-dioxane. A scheme for the process is proposed.

  2. 2.

    A catalytic ionic fragmentation was discovered of some perfluoro-4-oxo-1,3-dioxolanes containing a fluoroanhydride group to give trifluoroacetyl fluoride and carbon monoxide.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. S. Yuminov, S. V. Kartsov, L. E. Vinogradov & A. V. Fokin

  2. Ochtlnsk Scientific-Industrial Unification “Plastpolimer”, Leningrad

    V. S. Yuminov, S. V. Kartsov, L. E. Vinogradov & A. V. Fokin

Authors
  1. V. S. Yuminov
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  2. S. V. Kartsov
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  3. L. E. Vinogradov
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  4. A. V. Fokin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 396–398, February, 1988.

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Yuminov, V.S., Kartsov, S.V., Vinogradov, L.E. et al. Perfluorinated dioxolanes. 2. Reaction of perfluoro-4-oxo-1,3-dioxolanes with fluorine ion. Russ Chem Bull 37, 315–318 (1988). https://doi.org/10.1007/BF00957433

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  • DOI: https://doi.org/10.1007/BF00957433

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