Conclusions
The effect of the surface concentration of Bu4NF applied to silica gel and Aerosil on its catalytic capacity in condensation of benzaldehyde with fluorene was studied. The capacity of the Bu4NF applied to the support to pass into DMF solution was determined by the ionometric method. In the case of monolayer application of Bu4NF on silica gel, catalysis of the model reaction is heterogeneous in character.
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J. H. Clark, Chem. Revs.,80, 429 (1980).
N. S. Gulyukina, S. A. Medoks, B. N. Tarasevich, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 2053 (1986).
A. V. Kiselev and V. I. Lygin, Infrared Spectra of Surface Compounds [in Russian], Nauka, Moscow (1972), p. 97.
Structure and Properties of Adsorbents and Catalysts [Russian translation], Mir, Moscow (1968), p. 268.
Catalysis. Stereochemistry and Mechanisms of Organic Reactions [Russian translation], Mir, Moscow (1968), p. 260.
I. D. Chapman and M. L. Hair, J. Catal.,2, 145 (1963).
J. A. Rob van Veen, J. Chem. Soc. Chem. Communs.,23, 1656 (1985).
K. Camman, Working with Ion-Selective Electrodes, Springer-Verlag, New York (1979).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 375–378, February, 1988.
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Zhikhareva, M.G., Tarasevich, B.N., Kashin, A.N. et al. Properties of tetrabutylammonium fluoride applied to silica gel. Russ Chem Bull 37, 295–298 (1988). https://doi.org/10.1007/BF00957429
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DOI: https://doi.org/10.1007/BF00957429