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EPR spectra of branched fluorinated radicals, derivatives of 2-trifluoromethyl-2-hydroperfluoropentanethione-3

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

EPR was used to study new stable branched fluorinated radicals, adducts of organic and heteroorganic radicals with 2-trifluoromethyl-2-hydroperfluoropentathione-3. Predominant conformations and transition barriers between the radicals have been established.

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Literature cited

  1. J. Bolton, K. Chen, A. Lawrence, and P. de Mayo, J. Am. Chem. Soc., 97, 1832 (1975).

    Google Scholar 

  2. J. Scaiano and K. Ingold, J. Am. Chem. Soc.,98, 4727 (1976).

    Google Scholar 

  3. D. Forrest, K. Ingold, and D. Barton, J. Phys. Chem.,81, 915 (1977).

    Google Scholar 

  4. R. G. Gasanov, R. G. Petrova, T. D. Churkina, and R. Kh. Freidlina, Dokl. Akad. Nauk SSSR,274, 353 (1984).

    Google Scholar 

  5. B. L. Tumanskii, R. Nasirov, S. P. Solodovnikov, et al., Izv. Akad. Nauk SSSR, Ser. Khim. 2224 (1984).

  6. R. A. Bekker, V. Ya. Popkova, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 2627 (1980).

  7. P. Kruisie, K. Chen, P. Meakin, and I. Kochi, J. Phys. Chem., 78, 2036 (1974).

    Google Scholar 

  8. J. Worths and G. Bolton, Theory and Practical Applications of EPR [Russian translation], Mir, Moscow (1975), p. 184.

    Google Scholar 

  9. B. L. Tumanskii, N. N. Bubnov, V. R. Polishchuk, and S. P. Solodovnikov, Izv. Akad. Nauk SSSR, Ser. Khim., 2222 (1981).

  10. B. L. Tumanskii, A. M. Degtyarev, N. N. Bubnov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 2627 (1980).

  11. R. Kh. Freidlina, I. I. Kandror, and I. O. Bragina, Izv. Akad. Nauk SSSR, Ser. Khim., 1165 (1979).

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    B. L. Tumanskii, S. P. Solodovnikov, V. Ya. Popkova, N. N. Bubnov & I. L. Knunyants

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  1. B. L. Tumanskii
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  2. S. P. Solodovnikov
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  3. V. Ya. Popkova
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  4. N. N. Bubnov
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  5. I. L. Knunyants
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 317–321, February, 1988.

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Tumanskii, B.L., Solodovnikov, S.P., Popkova, V.Y. et al. EPR spectra of branched fluorinated radicals, derivatives of 2-trifluoromethyl-2-hydroperfluoropentanethione-3. Russ Chem Bull 37, 242–245 (1988). https://doi.org/10.1007/BF00957418

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  • DOI: https://doi.org/10.1007/BF00957418

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