Skip to main content
SpringerLink
Log in

Kinetics of overall decomposition of hydroxyhydrotrioxides

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The decomposition of hydroxyhydrotrioxides is described by a first order equation. The electron-donor substituents increase the stability of the hydrotrioxides.

  2. 2.

    There is a compensational effect for the preexponential factors and energies of activation of thermal overall decomposition of (CH3)2C(OH)OOOH in solvents CHCl3, CCl4. CH3CN, n-C6H14, (C2H5)2O and in C2H5OH-H2O mixtures.

  3. 3.

    The influence of the solvent on the rate constant of the overall decomposition of (CH3)2C(OH)OOOH is described for the range when the Koppel'-Pal'm equation holds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. N. Ya. Shafikov, R. A. Sadykov, V. V. Shereshovets, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1923 (1981).

  2. D. E. Stary, D. E. Emge, and R. W. Murray, J. Am. Chem. Soc.,98, 1880 (1976).

    Google Scholar 

  3. F. Kovac and B. Plesnicar, J. Am. Chem. Soc.,101, 2677 (1979).

    Google Scholar 

  4. W. A. Pryor, N. Onto, and D. F. Church, J. Am. Chem. Soc.,104, 5813 (1982).

    Google Scholar 

  5. V. V. Shereshovets, V. D. Komissarov, V. D. Maslennikov, and N. I. Kobal'nova, Izv. Akad. Nauk SSSR, Ser. Khim., 2631 (1982).

  6. A. Weissberger, E. Proskauer, G. Riddick, and E. Toops, Organic Solvents, 3rd ed., Wiley-Interscience, New York (1971).

    Google Scholar 

  7. P. S. Nangia and S. W. Benson, J. Am. Chem. Soc.,102, 3105 (1980).

    Google Scholar 

  8. D. Swern, Organic Peroxides, Vol. 3, Wiley Interscience, New York-London-Sydney-Toronto (1972), p. 32.

    Google Scholar 

  9. V. L. Antonovskii, Organic Peroxy Compounds [in Russian], Khimiya, Moscow (1972), p. 17.

    Google Scholar 

  10. A. I. Rakhimov, Chemistry and Technology of Organic Peroxy Compounds [in Russian], Khimiya, Moscow (1979), p. 32.

    Google Scholar 

  11. S. G. Entelis and R. P. Tiger, Reaction Kinetics in Liquid Phase [in Russian], Khimiya, Moscow (1973), p. 278.

    Google Scholar 

  12. V. A. Pal'm, Principles of Quantitative Theory of Organic Reactions [in Russian], Khimiva, Leningrad (1977).

    Google Scholar 

  13. N. S. Tsvetkov, V. Ya. Zhukovskii, R. G. Makitra, and Ya. N. Pirig, Reactsion. Sposobn. Organ. Soedin.,16, 273 (1979).

    Google Scholar 

  14. A. Uri and A. Tuulmets, Reactsion. Sposobn. Organ. Soedin.,20, 567 (1983).

    Google Scholar 

  15. Yu. A. Zhdanov and V. I. Minkin, Correlational Analysis in Organic Chemistry [in Russian], Izd-vo Rostov Univ. (1966), p. 312.

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa

    V. V. Shereshovets, F. A. Galieva & V. D. Komissarov

Authors
  1. V. V. Shereshovets
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. F. A. Galieva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. D. Komissarov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 304–309, February, 1988.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shereshovets, V.V., Galieva, F.A. & Komissarov, V.D. Kinetics of overall decomposition of hydroxyhydrotrioxides. Russ Chem Bull 37, 230–234 (1988). https://doi.org/10.1007/BF00957415

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00957415

Keywords

Search

Navigation